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The Entropy of the Universe Does Not Decrease 📂Thermal Physics

The Entropy of the Universe Does Not Decrease

Theorem

The entropy of the universe does not decrease.

Explanation

The first thing one notices upon seeing the proposition above is that ‘it sounds kind of cool’. But the truly cool person is the one who understands this mathematically, so let’s strive to become such a person.

Proof

We need the assumption that this universe is unique, and therefore that nothing like an ‘outside’ of this universe exists.

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As shown above, consider a cyclic process where $A \to B$ is irreversible and $B \to A$ is reversible. Since this process contains an irreversible process anyway, it is irreversible as a whole.

Clausius Theorem

In a cyclic process, the following holds.

$$ \oint {{\delta Q} \over {T}} \le 0 $$

By the Clausius theorem, the following holds.

$$ \oint {{\delta Q} \over {T}} = \int_{A}^{B} { { \delta Q } \over { T }} + \int_{B}^{A} { {{ \delta Q_{\text{rev} } } \over { T }} } \le 0 $$

Rearranging the upper and lower limits gives the following.

$$ \int_{A}^{B} { { \delta Q } \over { T }} \le \int_{A}^{B} { {{ \delta Q_{\text{rev} } } \over { T }} } $$

Definition of Entropy

The $S$ satisfying the following equation is defined as entropy.

$$ dS = {{ \delta Q_{\text{rev} } } \over { T }} $$

By the definition of entropy, we obtain the following.

$$ \int_{A}^{B} { { \delta Q } \over { T }} \le d S $$

If the universe is the one and only and there is nothing beyond it, it cannot exchange heat energy with an outside. Therefore, when we regard the universe as the whole system, every process is adiabatic, and mathematically we must have $\delta Q = 0$. Putting this together, $dS \ge 0$, so the entropy of the universe cannot decrease.